WebFeb 8, 2024 · Two Pd n L 2n (n=2, 12) type metal-organic cages (MOCs) decorated with anthracene groups have been successfully functionalized by a covalent post-synthetic … WebFeb 18, 2024 · The covalent post-synthetic modification was the first successfully reported post-synthetic functionalization technique . So far, covalent transformations of the organic linkers are the most extensively studied PSM type in MOF chemistry, such as amide coupling, imine condensation, bridging hydroxyl groups within the SBUs, etc.
Postsynthetic Modification of a Covalent Organic Framework …
WebCovalent PSM has proven a tool for introducing diverse chemical functional groups over the surface of MOFs framework. Materials Research ... View in full-text Similar publications … WebMar 15, 2024 · To date, introduction the functional groups in a large degree still not been explored due to the absence of reactive groups. Covalent postsynthetic modification … hal cr ffxiv
Advances in luminescent metal-organic framework sensors
WebMay 1, 2024 · Therefore, PSM provides a potential alternative way to obtain 3D COFs with desired functionality and an effective methodology to diversify their family. Download : Download high-res image (718KB) Download : Download full-size image Figure 5. Post-synthetic modification of 3D covalent organic frameworks (COFs). WebFor covalent or dative PSM, the MOF normally needs to have a reactive group present on a linker. This group is often referred to as a ‘tag’, which is defined as a group or … WebCovalent drugs refer to therapeutic agents that engage their corresponding target via covalent bond formation. 1 Covalent drugs are appealing over their noncovalent … halcroft rise wigston